tpe/tpr plastic material dual material applications

tpe/tpr plastic material dual material applications   Due to the popularity of the majority of consumers, the application of dual materials in recent years has formed a major trend, the application range is extremely wide, from toothbrush handle, comb handle, cleaning brush handle, knife handle, scissor handle and other daily necessities to flashlight handle, hair dryer handle, iron handle, electric toothbrush and other small household appliances, manufacturers are always trying to add a layer of TPE, so that the product more diversified. The market is expanding and its applications will become more widespread.   Generally speaking, TPE dual material injection molding can produce the following functions in product design.   1. To make the product surface with a soft and comfortable feeling   2. Make the product with anti-slip function   3. Improve the impact resistance of products   4. Increase the added value of old products and enhance the product grade   5. Processing method   1. Multiple Material Molding (MMM)   Multiple Material Molding (MMM) is processed by multi-material injection molding machine (commonly known as two-color machine), which is generally divided into two different designs, such as right angle injection table arrangement and balanced injection table arrangement. The right-angle two-color machine can be matched with a variety of two-color mold operation methods, such as: turntable type, core rotation, mold core sinking, live door separation, mold core sliding, etc. Two (or more) kinds of plastics are injected into different mold cavities at the same time to achieve the effect of multi-color or multi-material.   Its advantages are briefly as follows.   1. Short production cycle and higher output than traditional methods   2. Stable product quality and low scrap rate.   3. Stronger material bonding force and less defects on the bonding surface.   4. It is possible to manufacture more complex design of two-material products.   2. Insert Molding   Insert Molding is also known as the two-step method. This method is performed on a conventional or upright injection molding machine. This method requires two sets of molds and two injection molding machines. The pre-made hard plastic parts are fixed in the mold cavity of the second set of molds in the form of inserts, and then the TPE is injected into the hard plastic parts to achieve the effect of multi-color and multi-material.   Soft and hard material combination   In the application of dual material co-molding, different hard plastics are used for different products, such as PP for brushes, and ABS, PC or PA (nylon) for home appliances. Because the characteristics of each specification or variety of TPE are different, and a single specification of TPE can not have good bonding ability with every kind of hard plastic, so in the soft and different hard materials, it is necessary to cooperate with different specifications of TPE, in order to achieve the best bonding effect.   What kind of adhesive can be co-molded with TPE?   PP, PE   ABS, PC, ABS/PC Alloy   PA66, PA+GF   SAN, K-RESIN, PS, HIPS, PMMA


Application of TPE/TPR thermoplastic elastomer in the market

TPE/TPR thermoplastic elastomer flame retardant technology, high efficiency, high heat and light stability, low toxicity, low smoke, low corrosion, low impact on processing and mechanical properties, will not cause environmental pollution.    TPE\TPR thermoplastic elastomer graft modification, improve the adhesion or solubility of polypropylene with metals, polar plastics, inorganic fillers.   TPE\TPR thermoplastic elastomer blending modification, plastic blending modification refers to a resin mixed with one or more other resins (including plastic and rubber), so as to change the original resin properties of a modification method. Blends of plastics, also known as polymer alloys, is one of the most effective way to develop new polymer materials, but also the main way to achieve high performance and refinement of existing plastic varieties.   Thermoplastic elastomer TPR/TPE in light industrial applications: hand tools, power tools, anti-drug mask, casters, non-slip stirrups, pliers handle, a variety of racket grip, bicycle, motorcycle grip, luggage suitcase grip, cutlery grip, knife handle, flashlight grip, camera, digital camera grip, ammonium button, remote control button, computer keyboard, wire connectors, plugs, electric razor grip cover rubber, audio and speaker elastic accessories   Thermoplastic elastomer TPR/TPE in daily necessities: dishwasher, washing machine, clothes dryer, vacuum cleaner and other home appliances rubber gasket or parts, handle set, toothbrush handle, bellows, telescope, soft toys, high transparent alternative silicone pacifier, spoon, shower elastic parts, sanitary ware series, soft tablecloth, curtain, gift box, refrigerator box, non-slip mat, rubber floor mop, glass scraper Rubber edge food, beverage, cosmetic, sanitary and medical packaging scissors, toothbrushes, power tools, sports equipment grips or parts kitchen tools, storage containers lids or seals hand tools, power tools, weed whackers and gardening equipment wheels, grips, buzzers, tubing, belts, joints and soft parts for children's toys wire, cable sleeves, connectors and outer layers   Thermoplastic elastomer TPR/TPE in automotive parts applications: parts in the hood, such as clean air ducts, fuel line sheathing, control air box, isokinetic universal joint (CVJ) and oil filter seals. Body and suspension sheathing, such as weatherseals, wrap-around window seals, and lightweight sealing materials. Interior parts, such as airbag covers, front seat control panel skins   Thermoplastic elastomer TPR/TPE in the application of sports and cultural goods: pen set rubber parts, diving equipment, mouse ball, chest protector, tooth guard, (golf, ski poles) rubber shaft, (tug) hose, knee pads, masks, frog goggles, frog shoes, swimming goggles, diving masks, ski goggles and goggle straps, grip, treadmill belt, ping pong paddle rubber, skate shock absorbers   Thermoplastic elastomer TPR/TPE in medical devices: medical saline bottle stopper, disposable syringe rubber stopper, ear wash ball, plasma bag, infusion bag, surgical gloves, medical protective clothing, medical hygiene rubber material, extruded hose, elastic suction ball, container, girdle Injection needle stopper, intravenous tube assembly with medicine bottle stopper, milk bottle nozzle, pacifier, cardiac shock device, EKG, cable sleeve for ECG monitor, laser surgical pen.   Thermoplastic elastomer TPR/TPE in the automotive industry: dust cover, sealing strip, exhaust gas purge tube, fender, airbag, audio damping ring, dashboard, bumper cover, steering wheel elastic grip, elastic soft seat cushion, elastic rubber strip, fender, footrest pad, spotlight cover rubber   Thermoplastic elastomer TPR/TPE in the construction industry: glass curtain wall, doors, and skylights with seals and seals decorative rolls, decorative strips, alternative PVC materials, buildings, roads, bridges with expansion joints   Thermoplastic elastomer TPR/TPE in the electrical packaging industry: high-voltage electrical connections, insulated wire and cable and sheathing, electronic components anti-static strips, composite pipe fittings, conductive pipe fittings.


Analysis of the causes and countermeasures of fusion joint marks during TPE/TPR molding

1.What is fusion mark   When the TPE melt fills the cavity, if two or more strands of melt have cooled at the front part when they meet, so that they cannot be completely fused, a linear groove is produced at the confluence, forming a fusion mark.   2. Analysis of the causes of fusion marks and countermeasures   2.1. Material temperature is too low.   Low-temperature melt material has poor divergence and convergence performance, easy to form fusion marks. If the TPE material inside and outside the surface in the same part of the fusion fine lines, often due to the material temperature is too low caused by poor fusion. In this regard, the barrel and nozzle temperature can be properly increased, or extend the injection cycle to promote the material temperature rise. At the same time, the amount of coolant passed through the mold should be restrained to properly increase the temperature of the mold.       In general, the strength of the TPE material fusion marks is poor, if the corresponding part of the mold fusion marks for local heating, improve the local temperature of the fusion parts of the molding parts, often improve the strength of the TPE|TPR plastic fusion parts. If, due to special needs, low-temperature molding process must be used, the injection speed and injection pressure can be appropriately increased, so as to improve the melt convergence properties. Can also be appropriate in the raw material formula with a small amount of additional lubricants to improve the fluidity of the melt.   2.2. Mold defects.   Try to use the gate form with less diversion and choose the gate position reasonably. Choose the gate position to avoid inconsistent filling rate and interruption of the mold flow. If possible, a little bit of glue should be used. In order to prevent the low temperature melt from being injected into the mold cavity to produce fusion marks, the mold temperature can be increased at the same time, set up cooling cavities in the mold.   2.3. Poor mold exhaust.   First of all, you should check whether the mold exhaust hole is blocked by the melt curing or other objects, and whether there are foreign objects at the gate. If there is still charring point after the blockage is cleared, the exhaust hole should be increased at the sink point of the mold, or by repositioning the gate, or by appropriately reducing the closing force and increasing the exhaust gap to speed up the sink flow. In terms of process operation, we can also take auxiliary measures such as reducing the material temperature and mold temperature, shortening the high-pressure injection time and reducing the injection pressure.   2.4. Improper use of mold release agent.   In the injection molding, generally only in the threads and other parts that are not easy to release the mold evenly coated with a small amount of release agent, in principle, the amount of release agent should be reduced as much as possible.   2.5 TPE material structure design is not reasonable.   If the wall thickness of TPE plastic parts designed too thin or thin thickness disparity and too many inserts, will cause poor fusion. When designing the structure of the plastic part, it should be ensured that the thinnest part of the plastic part must be greater than the minimum wall thickness allowed during molding. In addition, the use of inserts should be minimized and the wall thickness as much as possible to the same.   2.6. The fusion angle is too small.   Different rubber and plastic materials have their own extreme fusion angle. Two streams of material converge if the convergence angle is less than the ultimate fusion angle, there will be fusion marks, if greater than the ultimate fusion angle, fusion marks will disappear. The ultimate fusion angle value is generally around 135 degrees.   2.7. Other reasons.   When the use of raw materials, moisture or volatile content is too high, the mold in the oil stains are not clean, the mold cavity with cold material or melt within the fiber filler distribution is poor, mold cooling system design is unreasonable, the melt curing too fast, the temperature of the insert is too low, the nozzle hole is too small, the injector plasticizing ability is not enough, the plunger or injector barrel pressure loss, can lead to different degrees of bad fusion.   In this regard, in the operation process, should be taken for different situations, respectively, pre-drying of raw materials, regular cleaning of the mold, change the mold cooling water channel design, control the flow of cooling water, improve the temperature of the insert, change to a larger aperture nozzle, change to a larger size injection machine and other measures to be resolved.   The melt marks, in addition to causing the appearance of the parts, but also may lead to insufficient strength of the parts, easy to fracture, etc..


Analysis of injection molding temperature and shrinkage rate of tpe/tpr products

TPR, usually refers to styrenic thermoplastic elastomer SBS, SEBS and other resins and additives mixed into a dry molecular alloy of elastomers (TPES). As the most commonly used TPE refers to styrene elastomer alloy TPES, and the TPE in China generally refers to TPES elastomer, therefore, the TPE/TPR in this paper is based on SEBS, SBS base material modified materials.   The problem of TPE/TPR injection temperature -   Influencing factors: oil filling rate; SEBS/SBS molecular weight and molecular conformation (linear or star); product thickness; special material formulations and equipment and mold problems, etc.   1. The higher the oil-filling ratio, the lower the injection temperature should be.   2. The injection temperature of SEBS base material is higher than SBS base material, because the thermal stability of SEBS base material is better than SBS base material.   3. SEBS, SBS molecular weight, high injection temperature; star SEBS / SBS system, injection temperature is higher than the linear SEBS SBS system.   4. For special materials, such as TPE with sticky PA, the introduction of high melting point phase components in the formulation makes the injection temperature higher.   5. products with large thickness require higher injection temperature than products with thin thickness.   6. Equipment type or melt capacity, as well as mold design (including runner, inlet design and the number of cavities in a mold, etc.) will have an impact.   In terms of hardness and injection method, the recommended injection temperature range is as follows (the specific temperature is adjusted according to the TPE grade provided by the supplier combined with the actual processing situation).   1.TPE hardness 0C~15A super soft material, injection molding temperature 130~200℃;   2.TPE/TPR hardness 20~110A single material injection material, recommended injection temperature 140~230℃.   3. TPE/TPR covered PP, the recommended secondary injection temperature 170~200℃;   4. TPE/TPR encapsulated ABS,PC, the recommended secondary injection temperature is 180~220℃.   5. TPE/TPR coated PA, the recommended secondary injection temperature is 240~270℃.   6. TPR coated PS (HIPS, GPPS), the recommended secondary injection temperature is 160~190℃.   In short, about the TPE/TPR material injection temperature, the general supplier can only give a reference value according to the material type. It should also be combined with the product structure size, processing equipment and mold design and other factors to consider, and gradually adjust the most appropriate injection molding temperature according to the actual processing conditions.   TPE/TPR shrinkage rate, 1 ~ 3%, low hardness TPE shrinkage rate is larger, other formula system is the same, the filling amount of TPE shrinkage rate is smaller than the filling amount of small TPE.


TPE/TPR material injection molding color problem analysis

Color difference is a common defect in injection molding, and it is not uncommon to see batch scrapping of injection molding machine due to color difference of matching parts. There are many factors affecting color difference, including raw material resin, color masterbatch, mixing of color masterbatch and raw material, injection molding process, injection molding machine, mold, etc. Because of the wide range of factors involved, color difference control technology is also one of the more difficult technologies to master in injection molding. In the actual production process, we generally control the color difference from the following six aspects.   1. Eliminate the influence of injection molding machine and mold factors   To choose the injection molding machine with the same capacity as the main product, if the injection molding machine has problems such as material dead corner, it is better to replace the equipment. For the mold pouring system, exhaust slot, etc. causing color difference, can be solved by the corresponding part of the mold maintenance mold. The injection molding machine and mold problems must be solved first before organizing production to cut the complexity of the problem.   2. Eliminate the influence of raw material resin and color masterbatch   Control of raw materials is the key to completely solve the color difference. Therefore, especially when producing light-colored products, we cannot ignore the obvious influence of different thermal stability of raw material resin on the color fluctuation of products. In view of the fact that most injection molding manufacturers do not produce plastic masterbatch or masterbatch themselves, so that the focus of attention can be placed on production management and raw material inspection. In other words, we should strengthen the inspection of raw materials in the warehouse; use the same manufacturer and the same brand of masterbatch and masterbatch in the production as far as possible; for the masterbatch, we should carry out sample color test before mass production, not only to check with the last time, but also to compare in this time, if the color difference is not big, it can be regarded as qualified, if there is a slight color difference with the same batch of masterbatch, the masterbatch can be re-mixed and used again to reduce the color difference caused by the uneven mixing of the masterbatch itself. The color difference caused by the uneven mixing of the masterbatch itself. At the same time, we also need to focus on testing the thermal stability of the raw material resin and masterbatch, and we suggest the manufacturer to replace those with poor thermal stability.   3. Eliminate the influence of uneven mixing of masterbatch and masterbatch   Bad mixing of plastic masterbatch and color masterbatch will also make the product color change. After mixing the masterbatch and masterbatch mechanically, when feeding into the hopper through the lower suction material, the masterbatch will be separated from the masterbatch due to the electrostatic effect and easily adsorbed on the hopper wall, which will inevitably cause the change of masterbatch amount in the injection cycle and thus produce color difference. This will inevitably cause the amount of masterbatch to change during the injection cycle, thus resulting in color difference. This situation can be solved by taking the raw material into the hopper and then mixing it manually. Nowadays, many companies use feeder to add color masterbatch, which saves a lot of manpower and provides great help for color difference control, but many companies often have unsatisfactory results due to improper use. The amount of masterbatch added to the feeder at a fixed speed depends on the plasticizing time, which itself fluctuates and sometimes even fluctuates greatly, so to ensure a constant amount of feeding, the feeding time of the feeder needs to be fixed and the set time is less than the minimum plasticizing time. In the use of feeder need to pay attention to, because the feeder outlet is small, after using a period of time, may be due to the feeder screw in the accumulation of raw material powder particles caused by inaccurate feeding, or even cause the feeder to stop, so you need to regularly clean up.   4. Reduce the impact of barrel temperature on the color difference   Production often encountered due to a heating ring damage failure or heating control parts out of control long burn caused by barrel temperature changes dramatically, resulting in color differences. This kind of reason produces the color difference is easy to determine, the general heating ring damage failure produces color difference at the same time will be accompanied by uneven plasticization phenomenon, and heating control part of the uncontrolled long burning often accompanied by product gas spot, serious discoloration and even coking phenomenon. Therefore, it is necessary to check the heating part frequently during produ


TPE/TPR material cold resistance function and odor principle discussion

First of all, we need to know the principle of human smell. The reason why people feel the smell of fragrance and odor is actually the molecules of a certain substance diffused into the human nose, which makes the human olfactory organs produce a series of reflections and form specific information into the brain, thus forming a certain odor judgment, such as aroma, odor, etc. So the odors we smell are small molecules that are volatilized into the air by the product.   Speaking of small molecules volatilized into the air, we have to mention a parameter in the raw materials - VOC (volatileorganic compounds) volatile organic compounds. There are two possibilities for no taste, one is that the material volatile small molecules itself has no smell, such as water; rather, will not volatile small molecules at all, such as table salt and other solids. But there is only one possibility of having a smell, that is, small molecules can be volatilized, and small molecules have an odor.   So elastomer formulations are most likely to volatile is a variety of oils, oil is good or bad directly affect the size of the product odor; the second is the content of each of the other formulations material VOC, try to choose a small VOC content of raw materials. And elastomer all kinds of raw materials are synthesized when the various organic solvents, the smell is inevitable, so the smaller the VOC content, the lighter the smell of the product.   At the same time, processing and mixing to minimize the destruction of the long chain, temperature and shear force should not be too high, appropriate, and oil absorption should be sufficient, all in order to reduce VOC.   Cold performance in which pieces, the rubber molecular chain will be reduced with the temperature, the ability to reduce activity, hardness, modulus and molecular friction increased to a certain low temperature when the molecular chain freeze, hardening completely lose elasticity, rubber or elastomer on the "plasticized". This temperature is the Tg glass transition temperature, but not all low temperature resistant materials are marked with Tg, because for some non-crystalline materials does not apply.   The influence of each component of the formulation on the low temperature resistance factors, right.   1.SEBS/SBS base material   It can be said that TPE/TPR inside the most important is SEBS/SBS, the impact is also the largest. Styrene and butadiene are hard and soft, so the lower the styrene content, the better the low temperature resistance of TPE/TPR.   2.TPE/TPV base material   For non-crystalline elastomer materials, the lower the cross-link density, the better the low-temperature resistance of the material, no chemical cross-linking TPE natural than TPV low-temperature resistance is better.   3. The choice of softening oil   White oil and other oils can reduce the hardness of the elastomer, low temperature resistance also has some favorable impact, but in the white oil selection to try to choose a lower pour point of oil.   4. The choice of filler   Fillers can not be used as far as possible, if you must use, try to choose some soft or spherical fillers, although the addition of fillers will not significantly affect the Tg glass transition temperature, but will affect the low temperature hardness, modulus and the rate of increase in intramolecular friction, so need to consider.


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