Differences Between TPE Materials and Rubber


 

### Introduction

Rubber, a term frequently used in the chemical industry, refers to both natural and synthetic products. Often, there is confusion about whether rubber and elastomers are the same concept and if they can be used interchangeably. Specifically, what are the differences between thermoplastic elastomers (TPE) and rubber?

### Rubber

Rubber is a natural or synthetic product typically made from raw rubber. Raw rubber is a highly viscous elastic material. By adding curing agents such as sulfur or peroxides and then heating the mixture, raw rubber can be transformed into elastic rubber. This process is called "vulcanization." During vulcanization, chemical bonds form between different chain molecules of raw rubber, causing them to polymerize. The resulting product is elastic, and the process can only be reversed through thermal degradation.

### TPE Materials

TPE materials are elastomers that can be processed using thermoplastic methods. In contrast, rubber is a thermoset elastomer.

### Key Differences Between TPE and Rubber

1. **Processing and Recyclability:**
   - **TPE:** Can be processed using thermoplastic methods, such as injection molding and extrusion. The scrap and waste materials can be recycled and reused.
   - **Rubber:** Is a thermoset material, meaning it cannot be remelted or reprocessed once cured. Scrap and waste materials are not recyclable.

2. **Strength:**
   - **TPE:** Generally has lower strength compared to rubber.
   - **Rubber:** Often has higher strength due to the cross-linking that occurs during vulcanization.

3. **Physical and Chemical Properties:**
   - **TPE:** Exhibits plastic-like behavior when heated and elastic properties when cooled. TPE has physical cross-linking characteristics.
   - **Rubber:** Has chemical cross-linking, which gives it its elastic properties and makes it more durable and resistant to deformation.

### Summary

**Differences Between TPE Materials and Rubber**

TPE and rubber are distinct materials with different properties and processing methods. TPE is a thermoplastic elastomer that can be processed using thermoplastic methods and is recyclable. Rubber, on the other hand, is a thermoset elastomer that requires vulcanization and is not recyclable. TPE materials exhibit plastic-like behavior when heated and elastic properties when cooled, while rubber has chemical cross-linking that provides higher strength and durability. Understanding these differences is crucial for selecting the appropriate material for specific applications.