Understanding SBS and SEBS: Safety and Applications in TPE and TPR Materials


 

### Main Raw Materials of TPE and TPR

TPE (Thermoplastic Elastomer) primarily uses SEBS (Hydrogenated Styrene-Butadiene Block Copolymer) as its main raw material, while TPR (Thermoplastic Rubber) primarily uses SBS (Styrene-Butadiene Block Copolymer). Both are non-toxic high molecular materials.

### Composition and Properties

- **SBS (Styrene-Butadiene Block Copolymer):** SBS is synthesized from styrene monomers through free radical polymerization. It consists of polystyrene end blocks and a polybutadiene mid-block, forming a linear triblock copolymer.
- **SEBS (Hydrogenated Styrene-Butadiene Block Copolymer):** SEBS is derived from SBS through hydrogenation. It has polystyrene end blocks and a hydrogenated polybutadiene mid-block, resulting in an ethylene-butylenes copolymer. SEBS exhibits more stable physical and chemical properties compared to SBS, making it even safer and non-toxic.

### Consumer Perceptions and Safety Concerns

Customers and consumers often have biases against these materials, particularly because styrene, a monomer in SBS, was listed as a Group 2B carcinogen by the World Health Organization in 2017. This has led to concerns about the toxicity of polystyrene-based materials.

However, SBS, as a high molecular polymer, is non-toxic, odorless, and transparent. After polymerization in a chemical reactor, the high molecular material becomes relatively stable and cannot be broken down by the human body. When melted at high temperatures, it does not release toxic gases or substances.

SEBS, being hydrogenated SBS, has even more stable physical and chemical properties, making it even safer and non-toxic.

### Safety Certifications and Applications

Both SBS and SEBS have passed rigorous tests and obtained certifications such as FDA and ISO 10993, which are high-level certifications for food and medical applications. These materials are easy to process and offer excellent tactile properties and slip resistance, making them widely used in:

- **Food Packaging:** Safe and hygienic, ideal for packaging food products.
- **Medical Products:** Used in medical devices and equipment due to their biocompatibility and safety.
- **Household Items:** Commonly found in everyday products due to their versatility and safety.

### Summary

**Understanding SBS and SEBS: Safety and Applications in TPE and TPR Materials**

SBS and SEBS are both non-toxic, high molecular materials used in TPE and TPR. Despite initial concerns about the toxicity of styrene, SBS and SEBS have been proven safe through extensive testing and have received high-level certifications for food and medical use. Their ease of processing, excellent tactile properties, and slip resistance make them widely applicable in food packaging, medical products, and household items.